Phosphinofenchol or Metastable Phosphorane? Phosphorus Derivatives of Fenchol

Synthesis of Phosphorus Derivatives via Multicomponent Reactions

Stable derivatives of oxaphosphaphenanthrenes were prepared using multicomponent reactions of 3-bromo-2-naphthol, dialkyl acetylenedicarboxylate and trimethyl or triphenyl phosphite under microwave conditions with good yields. 

Isolable Phosphanylidene Phosphorane with a Sterically Accessible Two-Coordinate Phosphorus Atom**

Phosphanylidene-s-phosphoranes (RP=PR’3) are phosphorus analogues of alkylidene-s-phosphoranes (R2C=PR’3), better known as Wittig reagents. Phosphanylidene-s-phosphoranes are synthetically accessible in the free form (RP= PR’3) and also in the transition-metal-stabilized form (LnM !P(R)=PR’3). [1] The latter complexes are commonly used in both P=C bond generation and as a source of the phosphin...

synthesis of phosphorus derivatives via multicomponent reactions

Interplay between structure and superconductivity: Metastable phases of phosphorus under pressure

José A. Flores-Livas,1 Antonio Sanna,2 Alexander P. Drozdov,3 Lilia Boeri,4,5 Gianni Profeta,6 Mikhail Eremets,3 and Stefan Goedecker1 1Department of Physics, Universität Basel, Klingelbergstrasse 82, 4056 Basel, Switzerland 2Max-Planck Institut für Microstructure Physics, Weinberg 2, 06120 Halle, Germany 3Max-Planck Institut für Chemie, Chemistry and Physics at High Pressures Group Postfach 30...

Superconductivity in metastable phases of phosphorus-hydride compounds under high pressure

José A. Flores-Livas,1 Maximilian Amsler,2 Christoph Heil,3 Antonio Sanna,4 Lilia Boeri,3 Gianni Profeta,5 Chris Wolverton,2 Stefan Goedecker,1 and E. K. U. Gross4 1Department of Physics, Universität Basel, Klingelbergstr. 82, 4056 Basel, Switzerland 2Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States 3Institute of Theoretical and C...